Принцип соответственных состояний. Прогнозирование коэффициентов сжимаемости и фугитивности (стр. 3 из 4)
Значения для простого вещества
| Tr | Pr | ||||||
| 0,010 | 0,050 | 0,100 | 0,200 | 0,400 | 0,600 | 0,800 | |
| 0,30 | –3,708 | –4,402 | –4,696 | –4,985 | –5,261 | –5,412 | –5,512 |
| 0,35 | –2,471 | –3,166 | –3,461 | –3,751 | –4,029 | –4,183 | –4,285 |
| 0,40 | –1,566 | –2,261 | –2,557 | –2,848 | –3,128 | –3,283 | –3,387 |
| 0,45 | –0,879 | –1,575 | –1,871 | –2,162 | –2,444 | –2,601 | –2,707 |
| 0,50 | –0,344 | –1,040 | –1,336 | –1,628 | –1,912 | –2,070 | –2,177 |
| 0,55 | –0,008 | –0,614 | –0,911 | –1,204 | –1,488 | –1,647 | –1,755 |
| 0,60 | –0,007 | –0,269 | –0,566 | –0,859 | –1,144 | –1,304 | –1,413 |
| 0,65 | –0,005 | –0,026 | –0,283 | –0,575 | –0,862 | –1,023 | –1,132 |
| 0,70 | –0,004 | –0,021 | –0,043 | –0,341 | –0,627 | –0,789 | –0,899 |
| 0,75 | –0,003 | –0,017 | –0,035 | –0,144 | –0,430 | –0,592 | –0,703 |
| 0,80 | –0,003 | –0,014 | –0,029 | –0,059 | –0,264 | –0,426 | –0,537 |
| 0,85 | –0,002 | –0,012 | –0,024 | –0,049 | –0,123 | –0,285 | –0,396 |
| 0,90 | –0,002 | –0,010 | –0,020 | –0,041 | –0,086 | –0,166 | –0,276 |
| 0,93 | –0,002 | –0,009 | –0,018 | –0,037 | –0,077 | –0,122 | –0,214 |
| 0,95 | –0,002 | –0,008 | –0,017 | –0,035 | –0,072 | –0,113 | –0,176 |
| 0,97 | –0,002 | –0,008 | –0,016 | –0,033 | –0,067 | –0,105 | –0,148 |
| 0,98 | –0,002 | –0,008 | –0,016 | –0,032 | –0,065 | –0,101 | –0,142 |
| 0,99 | –0,001 | –0,007 | –0,015 | –0,031 | –0,063 | –0,098 | –0,137 |
| 1,00 | –0,001 | –0,007 | –0,015 | –0,030 | –0,061 | –0,095 | –0,132 |
| 1,01 | –0,001 | –0,007 | –0,014 | –0,029 | –0,059 | –0,091 | –0,127 |
| 1,02 | –0,001 | –0,007 | –0,014 | –0,028 | –0,057 | –0,088 | –0,122 |
| 1,05 | –0,001 | –0,006 | –0,013 | –0,025 | –0,052 | –0,080 | –0,110 |
| 1,10 | –0,001 | –0,005 | –0,011 | –0,022 | –0,045 | –0,069 | –0,093 |
| 1,15 | –0,001 | –0,005 | –0,009 | –0,019 | –0,039 | –0,059 | –0,080 |
| 1,20 | –0,001 | –0,004 | –0,008 | –0,017 | –0,034 | –0,051 | –0,069 |
| 1,30 | –0,001 | –0,003 | –0,006 | –0,013 | –0,026 | –0,039 | –0,052 |
| 1,40 | –0,001 | –0,003 | –0,005 | –0,010 | –0,020 | –0,030 | –0,040 |
| 1,50 | –0,000 | –0,002 | –0,004 | –0,008 | –0,016 | –0,024 | –0,032 |
| 1,60 | –0,000 | –0,002 | –0,003 | –0,006 | –0,012 | –0,019 | –0,025 |
| 1,70 | –0,000 | –0,001 | –0,002 | –0,005 | –0,010 | –0,015 | –0,020 |
| 1,80 | –0,000 | –0,001 | –0,002 | –0,004 | –0,008 | –0,012 | –0,015 |
| 1,90 | –0,000 | –0,001 | –0,002 | –0,003 | –0,006 | –0,009 | –0,012 |
| 2,00 | –0,000 | –0,001 | –0,001 | –0,002 | –0,005 | –0,007 | –0,009 |
| 2,20 | –0,000 | –0,000 | –0,001 | –0,001 | –0,003 | –0,004 | –0,005 |
| 2,40 | –0,000 | –0,000 | –0,000 | –0,001 | –0,001 | –0,002 | –0,003 |
| 2,60 | –0,000 | –0,000 | –0,000 | –0,000 | –0,000 | –0,001 | –0,001 |
| 2,80 | 0,000 | 0,000 | 0,000 | 0,000 | 0,000 | 0,000 | 0,001 |
| 3,00 | 0,000 | 0,000 | 0,000 | 0,000 | 0,000 | 0,000 | 0,002 |
| 3,50 | 0,000 | 0,000 | 0,000 | 0,001 | 0,000 | 0,000 | 0,003 |
| 4,00 | 0,000 | 0,000 | 0,000 | 0,001 | 0,000 | 0,000 | 0,004 |
Таблица 4.8
состояния Ли-Кеслера
| Pr | |||||||
| 1,000 | 1,200 | 1,500 | 2,000 | 3,000 | 5,000 | 7,000 | 10,000 |
| –5,584 | –5,638 | –5,697 | –5,759 | –5,810 | –5,782 | –5,679 | –5,461 |
| –4,359 | –4,416 | –4,479 | –4,547 | –4,611 | –4,608 | –4,530 | –4,352 |
| –3,463 | –3,522 | –3,588 | –3,661 | –3,735 | –3,752 | –3,694 | –3,545 |
| –2,785 | –2,845 | –2,913 | –2,990 | –3,071 | –3,104 | –3,063 | –2,938 |
| –2,256 | –2,317 | –2,387 | –2,468 | –2,555 | –2,601 | –2,572 | –2,468 |
| –1,835 | –1,897 | –1,969 | –2,052 | –2,145 | –2,201 | –2,183 | –2,096 |
| –1,494 | –1,557 | –1,630 | –1,715 | –1,812 | –1,878 | –1,869 | –1,795 |
| –1,214 | –1,278 | –1,352 | –1,439 | –1,539 | –1,612 | –1,611 | –1,549 |
| –0,981 | –1,045 | –1,120 | –1,208 | –1,312 | –1,391 | –1,396 | –1,344 |
| –0,785 | –0,850 | –0,925 | –1,015 | –1,121 | –1,204 | –1,215 | –1,172 |
| –0,619 | –0,685 | –0,760 | –0,851 | –0,958 | –1,046 | –1,062 | –1,026 |
| –0,479 | –0,544 | –0,620 | –0,711 | –0,819 | –0,911 | –0,930 | –0,901 |
| –0,359 | –0,424 | –0,500 | –0,591 | –0,700 | –0,794 | –0,817 | –0,793 |
| –0,296 | –0,361 | –0,437 | –0,527 | –0,637 | –0,732 | –0,756 | –0,735 |
| –0,258 | –0,322 | –0,398 | –0,488 | –0,598 | –0,693 | –0,719 | –0,699 |
| –0,223 | –0,287 | –0,362 | –0,452 | –0,561 | –0,657 | –0,683 | –0,665 |
| –0,206 | –0,270 | –0,344 | –0,434 | –0,543 | –0,639 | –0,666 | –0,649 |
| –0,191 | –0,254 | –0,328 | –0,417 | –0,526 | –0,622 | –0,649 | –0,633 |
| –0,176 | –0,238 | –0,312 | –0,401 | –0,509 | –0,605 | –0,633 | –0,617 |
| –0,168 | –0,224 | –0,297 | –0,385 | –0,493 | –0,589 | –0,617 | –0,602 |
| –0,161 | –0,210 | –0,282 | –0,370 | –0,477 | –0,573 | –0,601 | –0,588 |
| –0,143 | –0,180 | –0,242 | –0,327 | –0,433 | –0,529 | –0,557 | –0,546 |
| –0,120 | –0,148 | –0,193 | –0,267 | –0,368 | –0,462 | –0,491 | –0,482 |
| –0,102 | –0,125 | –0,160 | –0,220 | –0,312 | –0,403 | –0,433 | –0,426 |
| –0,088 | –0,106 | –0,135 | –0,184 | –0,266 | –0,352 | –0,382 | –0,377 |
| –0,066 | –0,080 | –0,100 | –0,134 | –0,195 | –0,269 | –0,296 | –0,293 |
| –0,051 | –0,061 | –0,076 | –0,101 | –0,146 | –0,205 | –0,229 | –0,226 |
| –0,039 | –0,047 | –0,059 | –0,077 | –0,111 | –0,157 | –0,176 | –0,173 |
| –0,031 | –0,037 | –0,046 | –0,060 | –0,085 | –0,120 | –0,135 | –0,129 |
| –0,024 | –0,029 | –0,036 | –0,046 | –0,065 | –0,092 | –0,102 | –0,094 |
| –0,019 | –0,023 | –0,028 | –0,036 | –0,050 | –0,062 | –0,075 | –0,066 |
| –0,015 | –0,018 | –0,022 | –0,028 | –0,038 | –0,052 | –0,054 | –0,043 |
| –0,012 | –0,014 | –0,017 | –0,021 | –0,029 | –0,037 | –0,037 | –0,024 |
| –0,007 | –0,008 | –0,009 | –0,012 | –0,015 | –0,017 | –0,012 | 0,004 |
| –0,003 | –0,004 | –0,004 | –0,005 | –0,006 | –0,003 | 0,005 | 0,024 |
| –0,001 | –0,001 | –0,001 | –0,001 | 0,001 | 0,007 | 0,017 | 0,037 |
| 0,001 | 0,001 | 0,002 | 0,003 | 0,005 | 0,014 | 0,025 | 0,046 |
| 0,002 | 0,003 | 0,003 | 0,005 | 0,009 | 0,018 | 0,031 | 0,053 |
| 0,004 | 0,005 | 0,006 | 0,008 | 0,013 | 0,025 | 0,038 | 0,061 |
| 0,005 | 0,006 | 0,007 | 0,010 | 0,016 | 0,028 | 0,041 | 0,064 |
Коэффициенты фугитивности, рассчитанные по уравнению
Значения для простого вещества
| Tr | Pr | ||||||
| 0,010 | 0,050 | 0,100 | 0,200 | 0,400 | 0,600 | 0,800 | |
| 0,30 | –8,778 | –8,779 | –8,781 | –8,785 | –8,790 | –8,797 | –8,804 |
| 0,35 | –6,528 | –6,530 | –6,532 | –6,536 | –6,544 | –6,551 | –6,559 |
| 0,40 | –4,912 | –4,914 | –4,916 | –4,919 | –4,929 | –4,937 | –4,945 |
| 0,45 | –3,726 | –3,728 | –3,730 | –3,734 | –3,742 | –3,750 | –3,758 |
| 0,50 | –2,838 | –2,839 | –2,841 | –2,845 | –2,853 | –2,861 | –2,869 |
| 0,55 | –0,013 | –2,163 | –2,165 | –2,169 | –2,177 | –2,184 | –2,192 |
| 0,60 | –0,009 | –1,644 | –1,646 | –1,650 | –1,657 | –1,664 | –1,671 |
| 0,65 | –0,006 | –0,031 | –1,242 | –1,245 | –1,252 | –1,258 | –1,265 |
| 0,70 | –0,004 | –0,021 | –0,044 | –0,927 | –0,934 | –0,940 | –0,946 |
| 0,75 | –0,003 | –0,014 | –0,030 | –0,675 | –0,682 | –0,688 | –0,694 |
| 0,80 | –0,002 | –0,010 | –0,020 | –0,043 | –0,481 | –0,487 | –0,493 |
| 0,85 | –0,001 | –0,006 | –0,013 | –0,028 | –0,321 | –0,327 | –0,332 |
| 0,90 | –0,001 | –0,004 | –0,009 | –0,018 | –0,039 | –0,199 | –0,204 |
| 0,93 | –0,001 | –0,003 | –0,007 | –0,013 | –0,029 | –0,048 | –0,141 |
| 0,95 | –0,001 | –0,003 | –0,005 | –0,011 | –0,023 | –0,037 | –0,103 |
| 0,97 | –0,000 | –0,002 | –0,004 | –0,009 | –0,018 | –0,029 | –0,042 |
| 0,98 | –0,000 | –0,002 | –0,004 | –0,008 | –0,016 | –0,025 | –0,035 |
| 0,99 | –0,000 | –0,002 | –0,003 | –0,007 | –0,014 | –0,021 | –0,030 |
| 1,00 | –0,000 | –0,001 | –0,003 | –0,006 | –0,012 | –0,018 | –0,025 |
| 1,01 | –0,000 | –0,001 | –0,003 | –0,005 | –0,010 | –0,016 | –0,021 |
| 1,02 | –0,000 | –0,001 | –0,002 | –0,004 | –0,009 | –0,013 | –0,017 |
| 1,05 | –0,000 | –0,001 | –0,001 | –0,002 | –0,005 | –0,006 | –0,007 |
| 1,10 | –0,000 | –0,000 | 0,000 | 0,000 | 0,001 | 0,002 | 0,004 |
| 1,15 | 0,000 | 0,000 | 0,001 | 0,002 | 0,005 | 0,008 | 0,011 |
| 1,20 | 0,000 | 0,001 | 0,002 | 0,003 | 0,007 | 0,012 | 0,017 |
| 1,30 | 0,000 | 0,001 | 0,003 | 0,005 | 0,011 | 0,017 | 0,023 |
| 1,40 | 0,000 | 0,002 | 0,003 | 0,006 | 0,013 | 0,020 | 0,027 |
| 1,50 | 0,000 | 0,002 | 0,003 | 0,007 | 0,014 | 0,021 | 0,028 |
| 1,60 | 0,000 | 0,002 | 0,003 | 0,007 | 0,014 | 0,021 | 0,029 |
| 1,70 | 0,000 | 0,002 | 0,004 | 0,007 | 0,014 | 0,021 | 0,029 |
| 1,80 | 0,000 | 0,002 | 0,003 | 0,007 | 0,014 | 0,021 | 0,028 |
| 1,90 | 0,000 | 0,002 | 0,003 | 0,007 | 0,014 | 0,021 | 0,028 |
| 2,00 | 0,000 | 0,002 | 0,003 | 0,007 | 0,013 | 0,020 | 0,027 |
| 2,20 | 0,000 | 0,002 | 0,003 | 0,006 | 0,013 | 0,019 | 0,025 |
| 2,40 | 0,000 | 0,002 | 0,003 | 0,006 | 0,012 | 0,018 | 0,024 |
| 2,60 | 0,000 | 0,001 | 0,003 | 0,006 | 0,011 | 0,017 | 0,023 |
| 2,80 | 0,000 | 0,001 | 0,003 | 0,005 | 0,011 | 0,016 | 0,021 |
| 3,00 | 0,000 | 0,001 | 0,003 | 0,005 | 0,010 | 0,015 | 0,020 |
| 3,50 | 0,000 | 0,001 | 0,003 | 0,004 | 0,009 | 0,013 | 0,018 |
| 4,00 | 0,000 | 0,001 | 0,003 | 0,004 | 0,008 | 0,012 | 0,016 |
Таблица 4.9 состояния Ли-Кеслера